Article 57PNE Orange Peels Used to Extract Valuable Metals From Spent Batteries

Orange Peels Used to Extract Valuable Metals From Spent Batteries

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Orange peels used to extract valuable metals from spent batteries:

Just because a lithium-ion battery no longer holds a charge doesn't mean it no longer holds any value. It still contains useful metals, which can now be reclaimed via a more eco-friendly technique - the key ingredient is orange peel waste.

[...] With that limitation in mind, scientists at Singapore's Nanyang Technological University tried using orange peels instead of the usual acids and hydrogen peroxide. More specifically, they utilized oven-dried orange peels that had been ground into a powder, combined with citric acid obtained from citrus fruit.

Doing so, the researchers were able to extract about 90 percent of the lithium, cobalt, nickel and manganese from spent lithium-ion batteries. This level of efficiency is roughly what had been achieved previously. Importantly, though, when using the orange peels, the residue was found to be non-toxic.

[...] The researchers used the reclaimed metals in new lithium-ion batteries, that have a charge capacity similar to that of commercially available models. Further testing is now being conducted, to see if the new batteries last for a comparable number of charge/discharge cycles.

A paper on the research, which is being co-led by Prof. Madhavi Srinivasan, was recently published in the journal Environmental Science & Technology.

Journal Reference:
Zhuoran Wu, Tanto Soh, Jun Jie Chan, Shize Meng, Daniel Meyer, Madhavi Srinivasan, and Chor Yong Tay. Repurposing of Fruit Peel Waste as a Green Reductant for Recycling of Spent Lithium-Ion Batteries. Environmental Science & Technology 2020 54 (15), 9681-9692DOI: 10.1021/acs.est.0c02873

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