Article 616DB Found: the 'Holy Grail of Catalysis'

Found: the 'Holy Grail of Catalysis'

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hubie
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upstart writes:

Found: The 'holy grail of catalysis'-turning methane into methanol under ambient conditions using light:

An international team of researchers, led by scientists at the University of Manchester, has developed a fast and economical method of converting methane, or natural gas, into liquid methanol at ambient temperature and pressure. The method takes place under continuous flow over a photo-catalytic material using visible light to drive the conversion.

[...] Industry has long sought an economical and efficient way to convert methane into methanol, a highly marketable and versatile feedstock used to make a variety of consumer and industrial products. This would not only help reduce methane emissions, but it would also provide an economic incentive to do so.

Methanol is a more versatile carbon source than methane and is a readily transportable liquid. It can be used to make thousands of products such as solvents, antifreeze and acrylic plastics; synthetic fabrics and fibers; adhesives, paint and plywood; and chemical agents used in pharmaceuticals and agrichemicals. The conversion of methane into a high-value fuel such as methanol is also becoming more attractive as petroleum reserves dwindle.

[...] By eliminating the need for high temperatures or pressures, and using the energy from sunlight to drive the photo-oxidation process, the new conversion method could substantially lower equipment and operating costs. The higher speed of the process and its ability to convert methane to methanol with no undesirable byproducts will facilitate the development of in-line processing that minimizes costs.

Explanatory video

Journal Reference:
An, Bing, Li, Zhe, Wang, Zi, et al. Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site, Nature Materials, 2022. (DOI: 10.1038/s41563-022-01279-1)

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