Concrete “Battery” Developed at MIT Now Packs 10 Times the Power

upstart writes:

Concrete "battery" developed at MIT now packs 10 times the power:

Concrete already builds our world, and now it's one step closer to powering it, too. Made by combining cement, water, ultra-fine carbon black (with nanoscale particles), and electrolytes, electron-conducting carbon concrete (ec3, pronounced "e-c-cubed") creates a conductive "nanonetwork" inside concrete that could enable everyday structures like walls, sidewalks, and bridges to store and release electrical energy. In other words, the concrete around us could one day double as giant "batteries."

As MIT researchers report in a new PNAS paper, optimized electrolytes and manufacturing processes have increased the energy storage capacity of the latest ec3 supercapacitors by an order of magnitude. In 2023, storing enough energy to meet the daily needs of the average home would have required about 45 cubic meters of ec3, roughly the amount of concrete used in a typical basement. Now, with the improved electrolyte, that same task can be achieved with about 5 cubic meters, the volume of a typical basement wall.

"A key to the sustainability of concrete is the development of 'multifunctional concrete,' which integrates functionalities like this energy storage, self-healing, and carbon sequestration. Concrete is already the world's most-used construction material, so why not take advantage of that scale to create other benefits?" asks Admir Masic, lead author of the new study, MIT Electron-Conducting Carbon-Cement-Based Materials Hub (EC^3 Hub) co-director, and associate professor of civil and environmental engineering (CEE) at MIT.

The improved energy density was made possible by a deeper understanding of how the nanocarbon black network inside ec3 functions and interacts with electrolytes. Using focused ion beams for the sequential removal of thin layers of the ec3 material, followed by high-resolution imaging of each slice with a scanning electron microscope (a technique called FIB-SEM tomography), the team across the EC^3 Hub and MIT Concrete Sustainability Hub was able to reconstruct the conductive nanonetwork at the highest resolution yet. This approach allowed the team to discover that the network is essentially a fractal-like "web" that surrounds ec3 pores, which is what allows the electrolyte to infiltrate and for current to flow through the system.

"Understanding how these materials 'assemble' themselves at the nanoscale is key to achieving these new functionalities," adds Masic.

Equipped with their new understanding of the nanonetwork, the team experimented with different electrolytes and their concentrations to see how they impacted energy storage density. As Damian Stefaniuk, first author and EC^3 Hub research scientist, highlights, "we found that there is a wide range of electrolytes that could be viable candidates for ec3. This even includes seawater, which could make this a good material for use in coastal and marine applications, perhaps as support structures for offshore wind farms."

At the same time, the team streamlined the way they added electrolytes to the mix. Rather than curing ec3 electrodes and then soaking them in electrolyte, they added the electrolyte directly into the mixing water. Since electrolyte penetration was no longer a limitation, the team could cast thicker electrodes that stored more energy.

The team achieved the greatest performance when they switched to organic electrolytes, especially those that combined quaternary ammonium salts - found in everyday products like disinfectants - with acetonitrile, a clear, conductive liquid often used in industry. A cubic meter of this version of ec3 - about the size of a refrigerator - can store over 2 kilowatt-hours of energy. That's about enough to power an actual refrigerator for a day.

While batteries maintain a higher energy density, ec3 can in principle be incorporated directly into a wide range of architectural elements - from slabs and walls to domes and vaults - and last as long as the structure itself.

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